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Paraffin is one of the most common and promising phase change materials to store and release thermal energy. The inadequacy of paraffin lies in its low thermal conductivity, which affects its further application on thermal energy storage. In this work, hollow fibers derived from pitch were spun. The graphitization (treated at 2773 K under argon atmosphere) induced the carbon atom arrangement and lattice order development, which endowed the hollow graphite fibers (HGFs) with good graphite structure. The HGFs applied as thermal additives into paraffin significantly improved its thermal conductivity. The high thermal conductivity of the HGFs/paraffin composite was achieved up to 2.50 W/(m·K) along the fiber axis, which displayed an over 680% enhancement as compared with that of the pure paraffin. The HGFs displayed significant improvement of the heat transfer rate and heat flow of paraffin, which indicated the promising potential application of the HGFs/paraffin PCM in thermal energy storage systems.

Preparation and Thermal Characterization of Hollow Graphite Fibers/Paraffin Composite Phase Change Material