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The nanometer zinc complex, formed in chloride-urea ionic liquid (IL), was studied with the objective of enhancing the mildew resistance of bamboo. The nano-Zinc complex layer was coated on the bamboo surface by a simple and mild heating process. The SEM analysis revealed that the morphology of the nanometer Zinc complex layer on the bamboo surface varied with the reaction time of bamboo in zinc chloride (ZnCl2)/urea ionic liquid. The result of EDS and FTIR analysis showed that zinc and chlorine were successfully coated on the surface of bamboo. In this study, it was found that the optimum condition was 2 h of reaction with 1:2 molar ratio of zinc chloride to urea, where the nano-Zinc complex layer on the bamboo surface was the most uniform and dense to present the bamboo with the strongest mildew resistance. The infection value of Trichoderma viride, Aspergillus niger V. Tiegh, and Penicillium citrinum Thom after 28 day was 0.

Zinc Complex Derived from ZnCl2-Urea Ionic Liquid for Improving Mildew Property of Bamboo