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The enthalpy of mixing of the ternary Cu –Sn–Zn system was measured using a Calvet-type calorimeter. The investigations were carried out along the three cross sections Cu : Sn = 1 : 2, 1 : 1, and 2 : 1. Zn was added in the concentration range between 0 and 50 at.%.

Comparison of thermodynamic data of the ternary Cu–Sn–Zn system, measured with the EMF and with the calorimetric method