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The different transformations occurring during the crystallisation of amorphous Mg 80 Cu 10 Y 10  and Mg 83 Ni 9 Y 8  alloys have been elucidated. The formation of several unknown metastable phases was observed. The present work confirms that such phases exhibit long-period structures originated by the periodic alignment of (Y, TM)-layers (TM: transition metal). The long-period stacking-ordered phase, identified in the crystallised Ni-containing alloy, is stable at higher temperatures than that in the Cu-containing alloy.

Development of long-period ordered structures during crystallisation of amorphous Mg 80 Cu 10 Y 10 and Mg 83 Ni 9 Y 8