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The influence of hydrogen on the crystallization of meltspun Cu 50 Ti 40 Al 10  amorphous alloy was studied by DSC, TEM, X-ray and electron diffraction. The isothermal crystallization kinetics of the as-quenched glass revealed that the most probable crystallization mechanism is nucleation and subsequent three dimensional diffusion controlled growth. A strong influence of hydrogen on the crystallization of this amorphous alloy was found. Hydrogenation leads to drastic decreasing of the thermal stability, due to phase separation in the amorphous state and to formation of nanocrystalline structure during crystallization. The activation energy of the nanocrystallization reaction was determined by the Kissinger method.

Crystallization of As-quenched and Hydrogenated CU 50 Ti 40 Al 10 Amorphous Alloy