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Two potential alternative core materials, diatomaceous earth (DE) and glass bubbles (GB), were considered for cost effective and long life-time vacuum insulation panels (VIP). The pore size distribution of the DE was determined quantitatively by mercury porosimetry and nitrogen sorption. The majority of pores in DE centered around 1 μm. The average pore size of GB was estimated to be 50 μm via scanning electron microscopy. Subsequently, the relationship between pore size and gaseous thermal conductivity was established using the Kaganer relation. Composites of DE and fumed silica (FS) showed remarkable insulating performance whereby thermal conductivity only rose by 11 mW/m.K as pressure increased to 10,000 Pa. A similar analysis on composites of GB and fumed silica showed an increment of 16 mW/m.K. It was estimated that the duration for a typical VIP to reach 10,000 Pa is approximately 50 100 years depending on the type of barrier used. [30] Hence, both composites are capable of providing long vacuum insulating service life. Furthermore, DE/FS composites would greatly reduce the cost of VIPs because of the inexpensive nature of DE. Both composites show superior life-time when compared to glass fibers, which are already commercially used in VIPs.

Vacuum insulation panel core materials and modelling the thermal conductivity of granular materials