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VIII CHAPTER 1. OVERVIEW 1 1.1 Hydrogen sulfide 1 1.2 Tire Derived Rubber Particles (TDRP) 2 1.2.1 Used tires and potential environmental problems 2 1.2.2 Tire Derived Rubber Particles (TDRP) 3 1.3 H2S removal by TDRP 4 1.4 Objectives 4 CHAPTER 2. LITERATURE REVIEW 6 2.1 Adsorption 6 2.1.1 Adsorption and absorption 6 2.1.2 Equilibrium isotherms and diffusion 7 2.2 Surface characteristics and analysis methods 8 2.2.1 Langmuir isotherm 8 2.2.2 BET theory 9 2.2.3 Oxygen containing functionalities 10 2.2.4 Metal concentration 11 2.2.5 Acid-base properties 13 2.2.6 Summary 13 2.3 Tire rubber compositions and properties 13

An investigation of H2S adsorption mechanisms on Tire Derived Rubber Particles (TDRP<sup>TM</sup>)