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Make the composite electrolyte by doping Al2O3 powders ,in the ratios of 1:0.02 and 1:0.0 4 respectively to the electrolyte masses, into initial powders of the electrolyte-BaZrCeYO made in t he method of Pechini. After 10 hours sintered at 1400 ℃ , the composite electrolyte was completed , XRD test carried out, respectively in the range of 500-800 ℃ , Ac impedance spectrum tested, and adopted the composite electrolyte impedance test and output characteristic. The results showed that: Al element in the calcinations process replaced B atoms of ABO3 perovskite structure into the crystal lattice; electrolyte impedance and cell impedance increased significantly when the doping of Al2O3 increased, and the output characteristic performance of single cell was significantly reduced.

Research on impact of BaZr0.1Ce0.7Y0.2O3- electrolyte doped with a small amount of Al2O3 on the proton conducting solid oxide fuel cell