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We use cellular automata simulations at a mesoscopic scale to describe the phenomenon governing the morphology of pitting corrosion. We show that spontaneous separation of anodic and cathodic reaction zones plays a major role in determining the shape of the corroded space. The location of these zones versus the corroded surface is a stochastic event that influences strongly the direction of the corrosion propagation.

Mesoscopic modeling of corrosion processes: pitting morphology evolution