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The sensitization mechanisms for photo-initiations comprised a sensitizer dyes such as 2, 8-diethyl-1, 3, 5, 7, 9-pentamethylbipyrromethene difluoroborate (EBP), 1, 3, 5, 7, 9-pentamethyl-bipyrromethene difluoroborate (HBP), and 2, 8-diethyl-1, 3, 5, 7-teramethyl-9-phenylbipyrromethene difluoroborate (PBP), and a radical generating reagent 3, 3′, 4, 4′-tetrakis(t-butylperoxycarbonyl) benzophenone (BTTB) in acetonitrile have been investigated by singe photon counting.

Substituent Effect in Sensitization Mechanisms of Pyrromethene Dyes in Solution.