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A pyrrolidine ring containing carbamate ester, pyrrolidine-2-ylmethyl-carbamic acid isobutyl ester has been synthesized. The newly developed pyrrolidine ring containing carbamate ester surpassed 1,2diaminocyclohexane derived carbamate ester in asymmetric Michael addition reactions in aqueous media providing Michael products with yields (up to 97%), syn diastereoselectivities (up to 97%) and enantioselectivities (up to 94%).

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The carbamate esters as organocatalysts in asymmetric Michael addition reactions in aqueous media: when pyrrolidine backbone surpasses 1,2-diaminocyclohexane