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This report brings new facts and achievements on the cineand tele-substitutions reactions published in the last fifteen years. The reactions occurred primarily in such systems as nitroarenes, metal homoarene complexes, and fiveor six-membered heteroarenes. Sometimes similar reactions were also observed in other systems, including non-aromatic. cineand tele-Substitution reactions are presented here independently of their mechanisms.

cine- and tele-Substitution reactions: review of work from 2002-2016