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2-Acetylbenzo[h]quinoline and 3-acetylbenzo[f]quinolines have been selectively synthesized in yields of 58% and 60%, respectively, by the reaction of benzo[h]quinoline and benzo[f]quinoline with ethanol and carbon tetrachloride catalyzed by Cu-containing catalysts. The molecular structure of 3-acetylbenzo[f]quinoline was confirmed by X-ray diffraction method.

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Synthesis of 2-acetylbenzo[h]- and 3-acetylbenzo[f]quinolines by the reaction of benzo[h]- and benzo[f]quinolines with C2H5OH and CCl4 catalyzed by Cu-containing catalysts