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The dew points of phosphorus vapor over Sn-P alloys containing 45 mol%P or lesshave been determined at temperatures ranging from 703 to 973 K. The dew consisting of metastable liquid phosphorus, rather than stable red phosphorus, was utilized. The vapor pressures of P2 and P4 were determined from the dew points. Thermodynamic activities and enthalpies of P and Sn were calculated from the vapor pressures. The liquidus line was determined from the temperature and composition dependence of the vapor pressure over coexisting liquid and Sn4P3.

Measurement of Vapor Pressure of Phosphorus over Sn&ndash;P Alloys by Dew Point Method

Measurement of Vapor Pressure of Phosphorus over Sn–P Alloys by Dew Point Method