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Amorphous and low-ordered photosensitive materials are not usually considered to be promising photocatalytic agents because of extremely short free charge carrier (FCC) lifetimes in their active components deprived of well-defined electronic structures. Using active supports favoring an efficient FCC separation in situ, it is possible to protect free charge carriers from the immediate recombination, so even the disordered photosensitive composites can be provided with important photocatalytic capacities. The examples of some environmental applications of this type of active materials, such as volatile organic compound (VOC) photocatalytic removal and bacteria sterilization, are presented in this paper.

international journal of chemical reactor engineering

SFGP 2007 - Photosensitive Composite Disordered Nanostructures over Acceptor Supports: Selective Free Charge Carrier Generators for Environmental Applications