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The present study examines the effect of hydrogen distribution (HD) along a Co/SiO2 catalyst bed on Fischer-Tropsch (FT) synthesis. The synthesis is performed under two pressures of 1.0 and 9.0 atm and different H2/CO ratios. The results are compared to those of the usual co-feed, in which both CO and H2 are introduced to the bed inlet. By HD strategy, the methane selectivity is suppressed by as much as 25% and the C11+ selectivity is enhanced up to 26%. CO conversion and product selectivity exhibited a strong dependence on the operating pressure and H2/CO ratio, when hydrogen is distributed.

Improving C 11+ Hydrocarbon Product Selectivity by Hydrogen Distribution in Fischer-Tropsch Synthesis