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Novel proposed processes for H2 production and energy generation such as partial oxidation of hydrocarbons (POX-MeO) and chemical looping process (CLP), respectively require the use of solid oxides as oxygen carriers. In POX-MeO the required oxygen for the partial oxidation of methane is provided by a transition metal oxide (MeO). First, H2 is produced through CH4+MeO = CO+H2+Me. Secondly, Me is re-oxidized through Me+O2 = MeO to regenerate the oxygen carrier. In the CL process, CH4 is being completely oxidized through CH2 + MeO = CO2 + H2O + Me producing heat and CO2 ready for sequestration. Finally, Me is re-oxidized using air to regenerate the Me back to MeO. In both processes the regenerated MeO is sent back to the initial step to result in a cyclic operation. Continuous exposure of MeO to Redox cycles frequently produces sinterization and MeO stabilization is needed to avoid loss of activity. The objective of this study is to investigate the stabilization effect of TiO2 in Co3O4 during Redox cycles to be used as an oxygen carrier using CoxTiOy type spinnels. Characterization of the synthesized samples included XRD, TPR, and SEM. Co2TiO4 and CoTiO3 spinnels were synthesized by solid state reaction.  TGA and TPR Redox performance cycles of Co3O4 produced sintering, while results using a Co2TiO4 spinnel structure suggest a strong stabilization effect of TiO2 on Co. Ten Redox cycles using H2 and CH4 as reducing agents and a mixture of O2/N2 as oxidizer resulted in fixation of Co to TiO2 avoiding sintering.

Redox Stabilization Effect of TiO 2 in Co 3 O 4 as Oxygen Carrier for the Production of Hydrogen through POX and Chemical Looping Processes