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A simple, general and efficient method has been developed for the conjugate addition of a variety of aliphatic and aromatic amines to electron deficient alkenes in the presence of a catalytic amount of manganese (II) chloride in methanol-water to produce the corresponding -amino derivatives in excellent yields at room temperature.

the open catalysis journal

Manganese (II) Chloride-Catalyzed Conjugated Addition of Amines to Electron Deficient Alkenes in Methanol-Water Medium~!2009-10-16~!2009-12-15~!2010-03-30~!