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A network of ZrO2 nanorods was prepared using the porous biomembranes as templates. The sample was char- acterized by SEM, XRD and nitrogen physicosorption isotherm. ZrO2 nanoparticles were also prepared with a hydrother- mal method in order to compare with this network. The results showed that after being calcined at 800 o C for 24 h, a vol- ume contraction of ZrO2 nanorod network occurred accompanied by a phase transformation of tetragonal-to-monoclinic ZrO2; but the nanoparticles have grown into the large microparticles; as a result, ZrO2 nanorod network has a higher BET area (45.7 m 2 g -1 ) and a larger pore volume (0.20 cm 3 g -1 ). The calcined network showed a higher cataluminescence (CL) intensity of CO oxidation and a higher combustion activity than the calcined particles, which was ascribed its high surface area, as well as advanced pores.

Cataluminescence and Catalysis Properties of CO Oxidation Over Porous Network of ZrO2 Nanorods Synthesized by a Bio-Template