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The fractions of various clusters and single chromium atoms were calculated for a series of La1-0.2xSr0.2xCrxGa1- 1.2xMg0.2xO3- solid solutions (0.01 < x < 0.10) within the context of diluted solution and Heizenberg-Dirack-van Vleck models. An essential influence of both the nature and concentration of heterovalent diamagnetic substituent on the quanti- tative and qualitative composition of chromium atom clusters was shown. These clusters include also strontium, magne- sium atoms, and oxygen vacancies.

State of Chromium Atoms, Clustering, and Interatomic Interactions in Doped Lanthanum Gallate La(Sr)Ga(Cr,Mg)O3-δ