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Demi-macrocycles have additional sterochemical constrains resulting from the cyclic nature, which depend up on several factors such as macrocyclic ring size, 1-13 number and nature of chelate rings formed on co-ordination influence position of donor and central metal ion Zn(II) provides a number of coordination compounds because of its affinity towards different types of ligands and flexible coordination number ranging from two to eight the filled and shall does not offer crystal field stabilization on Zn(II) in this synthesis Zn(II) complex shows octahedral geometry demi-macrocyclic systems in a template reaction Zn(II) complex has a vitro, antibacterial activities. Zn(II) functions as an antioxidant. It is essential for protein synthesis.

Synthesis, Spectral Study of Demi-macrocycles of Ligand N2O2 with Zn (II) Ion