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Solid polymer electrolytes of poly(sodium 4-styrenesulfonate) as a polymer host and ammonium nitrate as an ionic dopant were prepared using a single-solvent via solution casting technique. According to the X-ray diffractogram and Fourier transmission infrared analyses, the solid electrolyte films were in an amorphous state and the coexistence of interaction between cation NH4 + and the polymer structure agrees that the complex film was successfully prepared. The scanning electron microscope observations revealed that the films appeared to be rough, flat, and irregularly shaped surface. The highest ionic conductivity (σ) of 3.16×10 Scm was achieved at room temperature (303K) for the sample containing 30 wt.% ammonium nitrate.

the malaysian journal of analytical sciences

ION-CONDUCTING POLYMER ELECTROLYTE FILMS BASED ON POLY (SODIUM 4-STYRENESULFONATE) COMPLEXED WITH AMMONIUM NITRATE: STUDIES BASED ON MORPHOLOGY, STRUCTURAL AND ELECTRICAL SPECTROSCOPY