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Cross-coupling reactions are among the most important chemical processes in the fine chemical and pharmaceutical industries. Widely used procedures such as the Heck, Suzuki and Sonogashira cross-coupling reactions and Buckwald-Hartwig aminations most commonly employ a palladium-based catalyst (1). Initially these reactions used simple Pd catalysts such as palladium chloride and palladium acetate,often in conjunction with a ligand.However, the need to carry out more challenging coupling reactions (for example those using less reactive aryl halides or pseudohalides, including aryl chlorides) has resulted in the development of more advanced Pd catalysts (1, 2).

Final Analysis: The Use of Metal Scavengers for Recovery of Palladium Catalyst from Solution