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Li(P3C2But2) reage com BrCH(SiMe3)2, via adicao oxidativa, formando um novo composto organofosforado de formula molecular P6C4But4 CHSiMe3 (1). O composto 1 foi caracterizado espectroscopicamente e sua estrutura molecular determinada atraves de difracao de raios X de monocristais. Juntamente com 1, foi caracterizado outro composto (2) com a mesma formula molecular, mas apresentando uma estrutura completamente saturada.

journal of the brazilian chemical society

Novel Organophosphorus Cage Compound Produced by an Unexpected Oxidative Coupling of 1,2,4-Triphosphole: Crystal and Molecular Structures of Two Isomers of Formula P6C4Bu t4 CHSiMe3