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The energy of molecular interaction for all fluids is represented by means of a single relation which takes into account both the excluded volume  V  τ  and the free volume ( V − V  τ ).

zeitschrift für physikalische chemie

A General Internal Potential Including Molecular Volume. Internal Energy and Equation of State of Fluids in Gas and Liquid Phases and under Critical Conditions: Study over a Wide Range of Temperature and Pressure