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Electron ionization cross sections for (N 2 O) n  clusters have been investigated near the threshold with a newly constructed crossed beams apparatus using a hemispherical electron monochromator (HEM) to monochromatize the primary electron beam. Exploratory test measurements including electron attachment studies to CCl 4  and CO and appearance energy (AE) determinations for some rare gases (Ar, Kr, Xe) and molecules (N 2 , O 2 , N 2 O, O 2 ) measured for calibration purposes showed that the accuracy of the energy scale is better than 10 meV exhibiting a good linearity and that AE´s derived for these compounds agree within 20 meV with known photoionization data when using a novel data handling procedure (involving a simultaneous non-linear weighted least-squares fit of two functions).

High Resolution Electron Ionization of N 2 O Clusters: Appearance Energies