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The self-association behaviour of relatively small hydrophobic organic components in aqueous mixtures has been investigated by the application of an NMR technique. The association A 22  parameter, which is essentially obtained from experimental intermolecular dipole-dipole relaxation data of   1 H nuclei and from NMR measurements of the self-diffusion coefficients of the organic solvents, has been determined. The composition dependence of the A 22  parameter allowed to point out the association behaviour of the organic components. Moreover, the effect of electrolytes and non electrolytes and of the temperature on the self-associating properties of the organic molecules has been studied.

Hydrophobic Interactions in Solution: A Nuclear Magnetic Resonance Approach