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The title compound was prepared by  N -benzylation of the corresponding secondary amine and transformation into its hydrobromide. It crystallizes from ethanol orthorhombically in the space group  P 2 1 2 1 2 1  with  a  = 1128.4(4),  b  = 2162.6(7),  c  = 769.2(2) pm.

Crystal structure of (1 S ,3 S )-2-benzyl-6-hydroxy-8-methoxy-1,3-dimethyl-1,2,3,4-tetrahydroisoquinoline hydrobromide