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C 10 H 13 NOS, monoclinic,  C 12/ c 1 (no. 15),  a  = 17.975(2) Å,  b  = 7.2265(9) Å,  c  = 17.343(2) Å, β = 110.687(3)°,  V  = 2107.6 Å 3 ,  Z  = 8,  R  gt  (F)  = 0.054,  wR  ref  (F  2  )  = 0.151,  T  = 223 K.

Crystal structure of o-ethyl N-(m-tolyl)thiocarbamate, SC(OC 2 H 5 )NH(C 6 H 4 CH 3 )