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Catalytic activities of catalase (CAT) immobilized on graphite - GMZ™ , soot - “NORIT ” and “PM -100” to mediate decomposition of 3-Cl-C 6 H 4 COOOH (3-CPBA)in acetonitrile have been investigated. Under these conditions, the kinetic parameters K m , k, E a , V max  , and Z o  were calculated. Conclusions on a probable mechanism of the catalytic process observed were drawn from the calculated values of ΔG*, ΔH*, and ΔS*. A quantitative UV-spectrophotometrical approach was used as the basic analytical tool. The electrochemical reduction of oxygen generated in enzyme catalysed 3-CPBA decomposition was examined with polarization curves method.

Catalytic Decomposition of 3-Chloroperoxybenzoic Acid by Immobilized Catalase in a Non-Aqueous Medium