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The reaction of Ni(OH) 2  and methanetrisulfonic acid trihydrate CH(SO 3 H) 3 ·3H 2 O (H 3 MTA·3H 2 O) in  N -methyl-pyrrolidone (NMP) leads to the trinuclear complex {Ni 3 [MTA] 2 (NMP) 8 } (triclinic,  P 1̅,  Z =1,  a =946.25(3),  b =1073.24(3),  c =1518.27(4) pm,  α =72.193(2),  β =87.398(2),  γ =89.389(2)°,  V =1466.49(7)×10 6  pm 3 ). The structural features of the methanetrisulfonate anions are tripodal as well as chelating coordination of the Ni 2+  ions. The thermal analysis has shown that the compound is first losing NMP molecules and that the solvent-free methanetrisulfonate finally decomposes yielding Ni 3 S 2 .

Tripodal methanetrisulfonate ligands in the trinuclear complex {Ni 3 [CH(SO 3 ) 3 ] 2 (NMP) 8 }