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The trifunctional silylamine MesSi(NHPh) 3  (Mes: 2,4,6-trimethylphenyl) was prepared by standard methods from MesSiCl 3  and LiNHPh. Lithiation of MesSi(NHPh) 3  and subsequent reaction with copper(I) benzoate afforded the nonanuclear cluster complex [Cu 9 {MesSi(NPh) 3 } 2  (PhCO 2 ) 3 ]·2toluene. The cluster core consists of three copper atoms which are coordinated almost linearly by the nitrogen atoms of two adjacing MesSi(NPh) 3  units. Additionally, each of the silylamide nitrogen atoms is connected to a peripheral copper atom and the peripheral copper atoms are linked by  μ  2 - κ ( O , O ′) bridging benzoate groups. The observed Cu–N distances are in the range 189.6(4)–196.7(3) pm.

Synthesis and crystal structure of the copper silylamide cluster compound [Cu 9 {MesSi(NPh) 3 } 2 (PhCO 2 ) 3 ]