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Based on 2-(4-carboxyphenyl)imidazo[4,5- f ]-1,10-phenanthroline (HNCP) and 2,5-thiophenedicarboxylate (TDC 2− ) ligands, three new lanthanide-containing (Sm, Nd, and Pr) compounds, [Sm(NCP)(TDC)]  n   ( 1 ), [Nd(NCP)(TDC)]  n  ·2 n (H 2 O) 0.5  ( 2 ), and [Pr(NCP)(TDC)]  n  · n (H 2 O) 0.5  ( 3 ), have been synthesized using the hydrothermal method and structurally characterized using single-crystal X-ray diffraction. Structural analyses have revealed that compounds  1–3  are 3D isostructural metal-organic frameworks in which the [Ln 2 (COO) 4 ] dimers can be regarded as 6-connecting nodes, and the TDC 2−  and NCP −  ligands are simplified as connectors to achieve the double interspersed 3D networks with the point symbol {4 12 ·6 3 }. Thermogravimetric analysis has illustrated that the rigid architecture contributes to superior thermal stability with a thermal decomposition temperature of more than 400°C for the resulting metal-organic frameworks.

zeitschrift für naturforschung b

Lanthanide(III) complex metal-organic frameworks with a phenanthroline-carboxylate derivate and 2,5-thiophenedicarboxylate coligand: hydrothermal synthesis, crystal structure, and high thermostability