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Two metal-organic coordination polymers constructed from tris( p -carboxylphenyl)phosphine oxide (TPOH 3 ), namely, [Zn(TPOH)(2,2′-bipy)(H 2 O)·H 2 O·DMF]  n   ( 1 ) and [Zn 2 (TPOH) 2 (1,4-bix) 2 ·5H 2 O]  n   ( 2 ) (2,2′-bipy=2,2′-bipydine, 1,4-bix=1,4-bis(imidazol-1-ylmethyl)benzene), were synthesized and identified by IR, elemental analysis and single-crystal X-ray diffraction analysis. Both of the 2,2′-bipy and 1,4-bix ligands tailor the complexes  1  and  2  into chain structures. The thermal behavior and solid state photoluminescence properties correlated with the corresponding structural features were investigated.

Two 1D zinc coordination polymers based on tris( p -carboxylphenyl)phosphine oxide: syntheses, structures and photoluminescence properties