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The hydrothermal reaction of 5,5′-[(pyridine-3,5-dicarbonyl)bis(azanediyl)]diisophthalic acid (H 4 L) with a Co(II) salt yields the new complex: [Co 3 (HL) 2 (H 2 O) 4 ] ( 1 ), which has been characterized by single crystal X-ray diffraction, IR, and elemental and thermogravimetric analyses. Complex  1  exhibits a binodal (4,8)-connected 2D net structure with (4 20 .6 8 )(4 6 ) 2  topology. The magnetic properties of  1  were also investigated.

A Co(II) complex based on a mixed N- and O-donor: synthesis, structural characterization, and properties