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The new compound [Mn 2 (bipy) 4 SbS 4 ](ClO 4 ) was prepared by a new synthetic route for the preparation of thioantimonates(V) that can be used even at room temperature. Mixing aqueous solutions of [Mn(bipy) 3 ](ClO 4 ) 2  and Na 3 SbS 4  · 9H 2 O leads to immediate crystallization of the pure compound. In the structure an SbS 4  3–  anion acts as a tetradentate bridge connecting two Mn 2+  cations of [Mn(bipy) 3 ] 2+  complexes (bipy = 2,2′-bipyridine). The compound features a hitherto unknown [Mn 2 (bipy) 4 SbS 4 ] +  cation. Bipy ligands of adjacent cations are arranged parallel to each other leading to weak off-center parallel  π - π  interactions stabilizing the crystals. Magnetic measurements indicate weak antiferromagnetic exchange interactions between the Mn 2+  centers.

Room temperature synthesis, crystal structure and selected properties of the new compound [Mn 2 (bipy) 4 SbS 4 ](ClO 4 )