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Two new complexes, {[Cd(immb)I 2 ]·DMF}  n   ( 1 ) and {[Cd 3 (immb)(btc) 2 ]·H 2 O}  n   ( 2 ) (immb = 2-(1 H -imidazol- 1-methyl)-6-methyl-1 H -benzimidazole, btc = 1,2,3-benzenetricarboxylate, DMF = dimethyl formamide), have been synthesized and characterized. Single crystal X-ray diffraction shows that  1  exhibits a chain structure constructed by immb ligands bridging Cd(II) ions. In  2 , Cd(II) ions are linked by immb ligands with bridging mode and btc 3–  anions with the  μ  2 - η  2 : η  1  bonding pattern leading to a 2D structure. Luminescent properties have been investigated in the solid state at room temperature.

Crystal structures and luminescence properties of two Cd(II) complexes based on 2-(1 H -imidazol-1-methyl)-6-methyl-1 H -benzimidazole