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A zinc complex of the 2-benzoylpyridine thiosemicarbazone (Hbpt) ligand, Zn(bpt) 2  · DMF, has been synthesized and characterized by elemental analysis, IR spectra and single crystal X-ray diffraction. The molecular structure has a Zn 2+  cation bonded to two perpendicular bpt ligands in a distorted octahedral geometry through two sulfur and four nitrogen atoms. The crystal contains a disordered DMF solvate molecule. Adjacent molecules are interconnected by means of hydrogen bonding generating a 1-D chain structure. The cytotoxic activity measurement indicates that the complex exhibits higher antitumor activity against lung cancer A549 cell lines than the free ligand.

Synthesis, Crystal Structure and Antitumor Study of a Zinc Complex of the 2-Benzoylpyridine Thiosemicarbazone Ligand