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The reactions of GlyOEt, L-AlaOMe, L-ValOMe or L-PheOMe with cycloheptadienyltricarbonyliron tetrafluoroborate afford the neutral 5-exo-amino substituted cycloheptadiene complexes [(η 4 -C 7 H 9 NHCHRCO 2 R’)Fe(CO) 3 ] which are formed as two diastereoisomers with R = Me, CHMe 2 , CH 2 Ph. The addition of GlyOEt, L-AlaOMe or L-VaOMe to the chiral [(η 3 -C 3 H 5 )Mo(Cp)(CO)(NO)]BF 4  gives the olefin complexes [(η 2 -CH 2 =CH-CH 2 - NH 2 CHRCO 2 R’)Mo(Cp)(CO)(NO)]BF 4 .

zeitschrift für naturforschung b

Addition von α-Aminosäureestern an den Cycloheptadienyl-Liganden von [(η 5 -C 7 H 9 )Fe(CO) 3 ] +  und den Allyl-Liganden des chiralen [(η 3 -C 3 H 5 )Mo(Cp)(CO)(NO)] +  / Addition of α-Amino Acid Esters to the Cycloheptadienyl Ligand of [(η 5 -C 7 H 9 )Fe(CO) 3 ] +  and of the Allyl Ligand of the chiral [(η 3 -C 3 H 5 )Mo(Cp)(CO)(NO)] +