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Complexes of the general composition Rh III (phpy) 2 (S∪E) with phpy −  = 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E −  = diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ ∗  intraligand triplet. For the complex with S∪E −  = 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions

zeitschrift für naturforschung b

Synthesis And Luminescence Of Rh III (phpy) 2 (S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate