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Treatment of the monomeric organogallium subiodide R(I)Ga-Ga(I)R 1 [R = C(SiMe 3 ) 3 ] with the diironcarbonylate anion [Fe 2 (CO) 8 ] 2−  yielded the red iron gallium compound Fe 2 (CO) 6 (μ-GaR) 3  2 in moderate yield. 2 may be described as an analogue of enneacarbonyldiiron Fe 2 (CO) 9 , the three bridging carbonyl groups of which are replaced by GaR ligands.

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The Organogallium Subhalide R 2 Ga 2 I 2  as Starting Compound for the Generation of a Transition Metal Gallium Complex – Synthesis of Fe 2 (CO) 6 (μ-GaR)3 [R = C(SiMe 3 ) 3 ]