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Crystalline nickel complexes with dianionic glucopyranoside ligands have been obtained by the reaction of methyl-D-glucopyranoside (Me-β -D-Glcp) or sucrose (Suc) with the cellulose solvent Ni-tren, an aqueous solution of [(tren)Ni(OH) 2 ], tren = tri(2-aminoethyl)amine. Crystals of a nickel complex of α,α-trehalose (α,α-Tre) form after the reaction of the disaccharide with Ni-Me 3  tren, the N,N′,N″-trimethyl analogue of Ni-tren. The metal-binding site is the O 3 ,O 4  diolate in [(tren)Ni(Me-β-D-Glcp3,4H −2 )] · 5.5H 2 O; in [(tren)Ni(Suc2’,3’H −2 )] · 6H 2 O, hydrogen-bond-supported O 2 ,O 3  chelation in the glucose part of the disaccharide is observed. The same metal-binding site as sucrose is exhibited by α,α-trehalose in [(tren)Ni(α,α-Tre2,3H −2 )] ・ 5H 2 O but without the support by an intramolecular hydrogen bond.

Polyol Metal Complexes, 45 [1]. D-Glucopyranosides as Ligands in Nickel Complexes