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Two new bimetallic complexes [Zn(phen) 3 ][Fe(CN) 5 (NO)] · 2 H 2 O · 0.25 MeOH, (1) and [(bipy) 2 (H 2 O)Zn(μ-NC)Fe(CN) 4 (NO)] · 0.5 H 2 O, (2), have been isolated (where phen = 1,10-phenanthroline and bipy = bipyridyl) and characterised by X-ray crystallography [as the 2 H 2 O · 0.25 CH 3 OH solvate for (1) and hemihydrate for (2)] infrared spectroscopy and thermogravimetric analysis. Substitution of phenanthroline for bipyridyl resulted in a cyano-bridged bimetallic species rather than two discrete mononuclear metal complexes. The bond angles of Fe-N-O were shown to be practically linear for both 1 [179.2(7)°] and 2 [178.3(3)°], and the Zn atoms have distorted octahedral geometry. The solvent molecules in both crystal lattices take part in forming hydrogen-bonded networks.

zeitschrift für naturforschung b

Synthesis, Characterisation and Structural Studies of [Zn(phen) 3 ][Fe(CN) 5 (NO)]·2H 2 O·0.25MeOH and [(bipy) 2 (H 2 O)Zn(μ-NC)Fe(CN) 4 (NO)]·0.5H 2 O