English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The silanimine tBu 2 Si=N-SitBu 3  reacts with the silyl azides tBuMe 2 SiN 3  or tBu 2 SiXN 3  (X = H, Me, F, Cl, Br) to form the corresponding tert-butyl-substituted 1-tri-tert-butylsilyl-4-triorganosilyl- 5,5-di-tert-butylsilatetrazolines. The silatetrazolines with chloro-di-tert-butylsilyl and bromo-di-tert-butylsilyl substituents can also be synthesized by treating two equivalents of tBu 2 SiXN 3  (X = Cl, Br) with the silanide tBu 3 SiNa. In the thermolysis of the silaterazolines the silanimines tBu 2 Si=N-SiXtBu 2  (X = F, Cl, Br, tBu) and silyl azides are formed in a first-order process. The silanimines tBu 2 Si=N-SiXtBu 2  (X= F, Cl, Br, tBu) have been trapped with acetone by en-reaction. The structure of (dimethyl-tert-butylsilyl)-substituted silatetrazoline has been determined by X-ray structure analysis.

zeitschrift für naturforschung b

Darstellung und Thermolyse tert-butylsubstituierter Silatetrazoline – Erzeugung der Silanimine tBu 2 Si=N-SiXtBu 2  (X = F, Cl, Br, tBu) Synthesis and Thermolysis of the tert-Butyl-Substituted Silatetrazolines – Formation of the Silanimines tBu 2 Si=N-SiXtBu 2  (X = F, Cl, Br, tBu)