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On exposure of trans-(n-Bu 4 N) 2 [Pt(SCN) 2 (ox) 2 ] to photochemical reduction (n-Bu 4 N) 2 - [Pt(SCN) 2 (ox)] (1) is formed. Further treatment with (SCN) 2  yields (n-Bu 4 N) 2 - [Pt(SCN) 4 (ox)] (2). The X-ray structure determination on a single crystal was performed of [(C 5 H 5 N) 2 CH 2 ][Pt(SCN) 4  (ox)] (triclinic, space group P1̅, a = 9.823(1), b = 14.850(1), c = 15.799(1) Å , α= 74.304(9), β= 86.268(9), γ= 87.455(9)°, Z = 4). Based on the molecular parameters of the X-ray determination the IR and Raman spectra have been assigned by normal coordinate analysis. The valence force constants of the symmetric axis S-Pt-S and of the asymmetrically coordinated S'-Pt-O* axes are f d (PtS) = 1.71, f d (PtS') = 1.92 (1), f d (PtS') = 2.02 (2) and f d (PtO • ) = 2.45 (1) and 2.24 (2) mdyn/Å. Taking into account increments of the trans influence a good agreement between observed and calculated frequencies is achieved. The NMR shifts are δ( 195 Pt) = 1967.7 (1) and 2930.8 ppm (2)

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Darstellung, Schwingungsspektren und Normalkoordinatenanalyse von (n-Bu 4 N) 2 [Pt(SCN) n (ox)], n = 2, 4, sowie Kristallstruktur von [(C 5 H 5 N) 2 CH 2 ][Pt(SCN) 4 (ox)] / Synthesis, Vibrational Spectra and Normal Coordinate Analysis of (n-Bu 4 N) 2 [Pt(SCN)n(ox)], n = 2, 4, and Crystal Structure of [(C 5 H 5 N) 2 CH 2 ][Pt(SCN) 4 (ox)]