English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

New copper(II) complexes with 8-hydroxyquinoline-2-carbaldehyde-N-methylnitrone (HL 1 ) (1) and pyridine-2-carbaldehyde-N-methylnitrone (L 2 ) (2) have been synthesized. The crystal structure of compound 1 consists of binuclear molecules Cu 2 (L 1 ) 2 (NO 3 ) 2  with the oxygen atoms of the hydroxy groups acting as bridges between the copper ions. The nitrone ligand in 1 is coordinated in a tridentate fashion forming five-and six-membered chelate rings, and the copper ions have a square-pyramidal environment with the bridging oxygen atoms in apical positions. In compound 2 Cu(L 2 ) 2 (NO 3 ) 2 , the copper atom adopts a distorted octahedral environment with bidentately coordinated nitrone ligands. In both cases the nitrone groups are involved in coordination via the oxygen atom. Compounds 1 and 2 have been studied by EPR, UV-VIS and IR spectroscopy. The free nitrone HL 1  has also been studied by X-ray diffraction as well as by IR and UV spectroscopy.

zeitschrift für naturforschung b

New Coordination Compounds Derived from Nitrone Ligands: Copper(II) Complexes with 8-Hydroxyquinoline-2-carbaldehyde- and Pyridine-2-carbaldehyde-N-methylnitrones