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Silicon, Silenes Two intramolecularly donor-stabilized silenes, l-(8-dimethylamino-l-naphthyl)-l,2,2-tris-(trimethylsilyl)silene (1), and l-[bis-2 ,6 -(dimethylaminomethyl)phenyl]-l,2 ,2 -tris(trimethyl-silyl)silene 2, were studied by 2 9 Si and C NMR spectroscopy, using polarization transfer techniques in order to determine coupling constants V (2 9 Si,2 9 Si) in = 1,2, 3) and '/ (2 9 Si,l3 C) together with isotope-induced chemical shifts 1 zA12/l3 C(2 9 Si) and Z\2 8 / ~9 Si(C).

zeitschrift für naturforschung b

29 Si- 29 Si and  29 Si- 13 C Indirect Nuclear Spin-Spin Coupling, and Isotope-Induced Chemical Shifts  1 Δ  12/13 C( 29 Si) and  1 Δ  28/29 Si( 13 C), Determined for Silenes Stabilized by Intramolecular N-Si Coordination