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The pure ternary phases on the line Sm 2 O 3 -SeO 2 : Sm 2 Se x O 3+2x  in thermodynamical equilibri­um have been synthesizied by solid state reactions and characterized by X-ray powder diffrac­tion, IR spectroscopy and DSC measurements. The existence of two new phases Sm 2 Se 1,5 O 6  and Sm 2 Se 4 O 11  was demonstrated besides the known phases Sm 2 Se 3,5 O 10 , Sm 2 Se 3 O 9  and Sm 2 SeO 5 . The thermal decomposition properties of all compounds have been determined by total pressure measurements and the thermodynamical data of the compounds have been derived from their decomposition function and C p -values. The phase diagram and the phase barogram have been estabilished using the results of DSC and total pressure measurements.

zeitschrift für naturforschung b

Thermochemische Untersuchungen zu den Systemen SE 2 O 3 -SeO 2 . II. Samariumselenoxide auf dem Schnitt Sm 2 O 3 -SeO 2  / Thermochemical Investigations of Systems SE 2 O 3 -SeO 2 . II. Samarium Selenium Oxides on the Line Sm 2 O 3 -SeO 2