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The thermodynamical data of solid Lanthanum Aluminium Bromide LaAl 3 Br 12  have been obtained by determination of the decomposition equilibria from total pressure measurements. For different compositions LaBr 3 /AlBr 3 , the barogram of the binary system LaBr 3 -AlBr 3  was constructed and from this and DTA the melting diagram was determined. The chemical trans­ port of LaBr 3  with AlBr 3  is suggesting the existence of two gaseous complexes LaAl 3 Br 12  and LaAl 2 Br 9 .

zeitschrift für naturforschung b

Thermisches und kalorisches Verhalten von festem LaAl 3 Br 12  und chemischer Transport von LaBr 3  mit AlBr 3  / Thermical and Calorical Behaviour of Solid LaAl 3 Br 12  and Chemical Transport of LaBr 3  with AlBr 3