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Consolidated stoichiometric mixtures of graphite fluoride (1) and magnesium (2) upon igni­ tion under argon atmosphere (0,1 MPa) yield very high flame temperature of ~ 5600 K as determined by infrared emission spectroscopy. The combustion product was analysed by X-ray powder diffraction and revealed the presence of magnesium fluoride and graphite as well as structurally low ordered carbon. A possible reaction mechanism is discussed.

Fluoreliminierung aus Graphitfluorid mit Magnesium / Defluorination of Graphite Fluoride Applying Magnesium Emst-Christian Koch